Chlorotrimethylsilane → (3-Bromophenyl)trimethylsilane

HRID 963000Notes

Reaction equation

Cl[Si:2]([CH3:5])([CH3:4])[CH3:3].[Br:6][C:7]1[CH:12]=[CH:11][CH:10]=[C:9](I)[CH:8]=1>>[Br:6][C:7]1[CH:12]=[CH:11][CH:10]=[C:9]([Si:2]([CH3:5])([CH3:4])[CH3:3])[CH:8]=1

Participants

Reactant 2

HCID 6397Chlorotrimethylsilane

HCID 11561Benzene, 1-bromo-3-iodo-

Product 1

HCID 4167050(3-Bromophenyl)trimethylsilane

Procedure

1-Bromo-3-trimethylsilanyl-benzene is prepared in a manner analogous to the procedure described in examples 1 and 1a utilizing chlorotrimethylsilane and 1-bromo-3-iodobenzene as the dihalo compound of formula (III).

Sources & evidence

ORD record: ord-f7b9334bdc0f4bce973059ff26d80140
Source dataset: uspto-grants-1998_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05760267

Reaction notes

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