Chlorotrimethylsilane → (3-Iodophenyl)(trimethyl)silane

HRID 963002Notes

Reaction equation

Cl[Si:2]([CH3:5])([CH3:4])[CH3:3].[I:6][C:7]1[CH:12]=[CH:11][CH:10]=[C:9](I)[CH:8]=1>>[I:6][C:7]1[CH:12]=[CH:11][CH:10]=[C:9]([Si:2]([CH3:5])([CH3:4])[CH3:3])[CH:8]=1

Participants

Reactant 2

HCID 6397Chlorotrimethylsilane

HCID 12270Benzene, 1,3-diiodo-

Product 1

HCID 12358196(3-Iodophenyl)(trimethyl)silane

Procedure

1-Iodo-3-trimethylsilanyl-benzene is prepared in a manner analogous to the procedure described in examples 1 and 1a utilizing chlorotrimethylsilane and 1,3-diiodobenzene as the dihalo compound of formula (III).

Sources & evidence

ORD record: ord-026811d97b754223aa6be5fba03537c5
Source dataset: uspto-grants-1998_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05760267

Reaction notes

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