HCID 86752694, compound → HCID 86752695, compound

HRID 963015Notes

Reaction equation

HRID 963015 reaction equation
FC(F)(F)S(O[C:7]1[C:12](/[CH:13]=[CH:14]/[C:15]#[C:16][C:17]2[CH:27]=[CH:26][C:20]([C:21]([O:23][CH2:24][CH3:25])=[O:22])=[CH:19][CH:18]=2)=[CH:11][C:10]([CH3:29])([CH3:28])[CH2:9][CH:8]=1)(=O)=O.FC(F)(F)S(O[C:38]1[C:43](/C=C/CCC2C=CC(C(OCC)=O)=CC=2)=[CH:42][C:41](C)([CH3:59])[CH2:40][CH:39]=1)(=O)=O>>[CH3:59][C:41]1[CH:42]=[CH:43][C:38]([C:7]2[C:12](/[CH:13]=[CH:14]/[C:15]#[C:16][C:17]3[CH:27]=[CH:26][C:20]([C:21]([O:23][CH2:24][CH3:25])=[O:22])=[CH:19][CH:18]=3)=[CH:11][C:10]([CH3:29])([CH3:28])[CH2:9][CH:8]=2)=[CH:39][CH:40]=1

Participants

3

Reactant 2

HCID 86752694HCID 86752694, compoundHCID 86752696HCID 86752696, compound

Product 1

HCID 86752695HCID 86752695, compound

Procedure

Following General Procedure A, ethyl (E)-4-(4-(2-(trifluoromethanesulfonyl)oxy-5,5-dimethyl-1,3-cyclohexadien-3-yl)but-3-ene-1-yn-1-yl)benzoate (Compound 21, 46 mg, 0.098 mmol) was converted into the title compound.

Sources & evidence

ORD record
ord-7aba1d7a0c164f97a9e7534f8515be3c
Source dataset
uspto-grants-1998_06
Patent number
US05760276

Reaction notes

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