Water → HCID 23675693, compound

HRID 963589Notes

Reaction equation

HRID 963589 reaction equation
[F:1][C:2]([F:24])([CH2:8][CH2:9][CH2:10][C:11]([F:23])([F:22])[C:12]([F:21])([F:20])[C:13]([F:19])([F:18])[C:14]([F:17])([F:16])[F:15])[C:3]([O:5]CC)=[O:4].[OH-].[Na+:26].O>CO>[F:1][C:2]([F:24])([CH2:8][CH2:9][CH2:10][C:11]([F:22])([F:23])[C:12]([F:20])([F:21])[C:13]([F:19])([F:18])[C:14]([F:15])([F:16])[F:17])[C:3]([O-:5])=[O:4].[Na+:26]

Participants

5

Reactant 3

HCID 962WaterHCID 14798Sodium HydroxideHCID 19082567HCID 19082567, compound

Product 1

HCID 23675693HCID 23675693, compoundYield 99.2%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Sodium 2,2,6,6,7,7,8,8,9,9,9-undecafluoro-nonanoate (60 g, 99% yield, formula above) was prepared from ethyl 2,2,6,6,7,7,8,8,9,9,9-undecafluorononanoate (61.5 g, 0.16 mol), sodium hydroxide (6.5 g, 0.163 mol), water (100 mL) and methanol (100 mL) according to the procedure of Example 7.

Sources & evidence

ORD record
ord-cb323ccbd66f43dcb358160a1d2e4d2a
Source dataset
uspto-grants-1998_06
Patent number
US05763552

Reaction notes

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