Diisobutylaluminumhydride → HCID 18359058, compound

HRID 963792Notes

Reaction equation

HRID 963792 reaction equation
[F:1][C:2]1[C:12]([F:13])=[C:11]([O:14][CH2:15][O:16][CH2:17][CH2:18][O:19][CH3:20])[C:10]([O:21][CH2:22][O:23][CH2:24][CH2:25][O:26][CH3:27])=[CH:9][C:3]=1[CH:4]=[CH:5]C([O-])=O.[H-].C([Al+]CC(C)C)C(C)C>CCCCCC>[F:1][C:2]1[C:12]([F:13])=[C:11]([O:14][CH2:15][O:16][CH2:17][CH2:18][O:19][CH3:20])[C:10]([O:21][CH2:22][O:23][CH2:24][CH2:25][O:26][CH3:27])=[CH:9][C:3]=1[CH:4]=[CH2:5]

Participants

4

Reactant 2

HCID 21225700DiisobutylaluminumhydrideHCID 131720705HCID 131720705, compound

Product 1

HCID 18359058HCID 18359058, compoundYield 81.2%

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Using the procedure of Stage C of Example 40, 44.3 g of the ester of Stage D and 230 ml of a molar solution of diisobutyl-aluminum hydride in hexane were reacted to obtain 32 g of the expected product.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-b5d229f462d54b00b412a1278db6e829
Source dataset
uspto-grants-1998_06
Patent number
US05763617

Reaction notes

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