HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzene → 1-(3-Acetoxy-2-fluoroprop-1-enyl)-1-(3,4-methylenedioxyphenyl)cyclopropane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzene | HCID 241 | — |
| Reactant | Acetyl chloride | HCID 6367 | — |
| Reactant | 1-(2-Fluoro-3-hydroxyprop-1-enyl)-1-(3,4-methylenedioxyphenyl)cyclopropane | HCID 54109861 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Product | 1-(3-Acetoxy-2-fluoroprop-1-enyl)-1-(3,4-methylenedioxyphenyl)cyclopropane | HCID 54149588 | 93% |
Reaction Steps
The method of Example 17 was repeated using acetyl chloride (1.4 ml), 1-(2-fluoro-3-hydroxyprop-1-enyl)-1-(3,4-methylenedioxyphenyl)cyclopropane (Example 14) (0.68 g), benzene (40 ml) and pyridine (0.26 ml) to yield the title compound (0.73 g, 93%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05763700 |
| Source dataset | uspto-grants-1998_06 |
| ORD ID | ord-8034765c2b54437e898085a52f01759c |
| Source note | uspto-grants-1998_06 |