Trichlorosilane → HCID 178421921, compound

HRID 964352Notes

Reaction equation

HRID 964352 reaction equation
[Cl:1][SiH:2]([Cl:4])[Cl:3].[Cl-:5].[Cl-].[CH2:7]([Zr:11]([CH3:33])(=[SiH2:32])([CH:22]1[C:30]2[C:25](=[CH:26][CH:27]=[CH:28][CH:29]=2)[CH:24]=[C:23]1[CH3:31])[CH:12]1[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=[C:13]1[CH3:21])[CH2:8][CH:9]=[CH2:10]>C1(C)C=CC=CC=1>[Cl-:1].[Cl-:5].[Cl:1][Si:2]([Cl:4])([Cl:3])[CH2:10][CH2:9][CH2:8][CH2:7][Zr:11]([CH3:33])(=[SiH2:32])([CH:22]1[C:30]2[C:25](=[CH:26][CH:27]=[CH:28][CH:29]=2)[CH:24]=[C:23]1[CH3:31])[CH:12]1[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=[C:13]1[CH3:21]

Participants

4

Reactant 2

HCID 24811TrichlorosilaneHCID 178448262HCID 178448262, compound

Product 1

HCID 178421921HCID 178421921, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

0.4 g (3 mmol) of trichlorosilane and 10 mg of H2PtCl6.6H2 O were added to a solution of 0.52 g (1 mmol) of (3-butenyl)(methyl)silanediyl[bis(2-methylindenyl)]zirconium dichloride in 5 ml of toluene. After stirring for 24 hours at room temperature, the excess trichlorosilane and the toluene were removed in an oil pump vacuum. This gives 0.69 g of an oil which no longer shows any resonance signals of the vinyl protons in the 1H-NMR spectrum.

Workup

  1. customthe excess trichlorosilane and the toluene were removed in an oil pump vacuum

Sources & evidence

ORD record
ord-d9b30cf90dfb42e997d0dc313d2e26bd
Source dataset
uspto-grants-1998_06
Patent number
US05767300

Reaction notes

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