Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ribonolactone → D-Ribonic acid (benzyl 2-benzyloxycarbonylamino-2,6-didesoxy-alpha-D-glucopyranosid-6-yl)-amide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ribonolactone | HCID 111064 | — |
| 반응물 | Benzyl 6-amino-2-benzyloxycarbonylamino-2,6-didesoxy-alpha-D-glucopyranoside | HCID 53644733 | — |
| 용매 | 1,4-Dioxane | HCID 31275 | — |
| 생성물 | D-Ribonic acid (benzyl 2-benzyloxycarbonylamino-2,6-didesoxy-alpha-D-glucopyranosid-6-yl)-amide | HCID 86752800 | — |
반응 단계
Benzyl 6-amino-2-benzyloxycarbonylamino-2,6-didesoxy-α-D-glucopyranoside (see Ex. 9.C.) and D-ribonic acid g-lactone were reacted as described in Ex. 14.A. and gave D-ribonic acid (benzyl 2-benzyloxycarbonylamino-2,6-didesoxy-α-D-gluco-pyranosid-6-yl)-amide, [α]+81.5° (c 0.2; dioxan), MS: m/z 551.4 ([M+H]+).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05767268 |
| 출처 데이터셋 | uspto-grants-1998_06 |
| ORD ID | ord-d5b4f10fe2f6464fa205d7e1f8a3eca5 |
| 출처 메모 | uspto-grants-1998_06 |