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HRID965376

反应详情

EQUATION

反应方程式

HRID 965376 的结构方程式

REACTANTS

反应物

2
结构：C=[N+]=[N-]
HCID9550

Diazomethane

CH2N2

结构：CC(=O)OC[C@H]1O[C@@H](n2cnc(C(=O)Cl)c2N=CN(C)C)[C@H](F)[C@@H]1OC(C)=O
HCID54164098

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)OC[C@H]1O[C@@H](n2cnc(C(=O)C=[N+]=[N-])c2N=CN(C)C)[C@H](F)[C@@H]1OC(C)=O
HCID53954749

未命名化合物

PROCEDURE

实验过程

In step 13, compound (19) is reacted with diazomethane at room temperature without being separated from the reaction solution, so that the 4-chlorocarbonyl group of compound (19) is converted into diazoacetyl group, affording 1-(3,5-di-O-acetyl-2-deoxy-2-fluoro-β-D-ribofuranosyl)-4-diazoacetyl-5-(dimethylaminomethyleneamino)imidazole [compound (20)].

WORKUP

后处理

  1. customwithout being separated from the reaction solution, so that the 4-chlorocarbonyl group of compound (19)