HRID967689

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(C)(c1ccc(O)cc1)c1ccc(O)cc1.ClCC1CO1

HCID62790

未命名化合物

结构：O=P(c1ccccc1)(c1ccc(O)cc1)c1ccc(O)cc1

HCID69930

p,p'-(Phenylphosphinylidene)bisphenol

C18H15O3P

PRODUCTS

生成物

结构：CC(C)(c1ccc(O)cc1)c1ccc(O)cc1.ClCC1CO1.O=P(c1ccccc1)(c1ccc(O)cc1)c1ccc(O)cc1

HCID131725191

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID7900

1-Methoxy-2-propanol

C4H10O2

PROCEDURE

实验过程

Bis(4-hydroxyphenyl)phenylphosphine oxide (196.0 g) and EPON 828 (782.0 g) were heated at 170° C. for 40 min. The clear dark brown resin was then diluted with 218 g of PGME and filtered hot through a pad of glass wool. Solution EEW: 454; % Solids: 88.7.

WORKUP

后处理

filtrationfiltered hot through a pad of glass wool

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-93620b649522495581d065ea13a6552d
来源数据集: uspto-grants-2005_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06955851B2
来源说明: uspto-grants-2005_10

反应 SMILES

[OH:1][C:2]1[CH:7]=[CH:6][C:5]([P:8](=[O:22])([C:15]2[CH:20]=[CH:19][C:18]([OH:21])=[CH:17][CH:16]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[CH:4][CH:3]=1.[CH3:23][C:24]([C:33]1[CH:38]=[CH:37][C:36]([OH:39])=[CH:35][CH:34]=1)([C:26]1[CH:31]=[CH:30][C:29]([OH:32])=[CH:28][CH:27]=1)[CH3:25].[CH2:40]1[O:42][CH:41]1[CH2:43][Cl:44]>CC(O)COC>[OH:1][C:2]1[CH:7]=[CH:6][C:5]([P:8](=[O:22])([C:15]2[CH:16]=[CH:17][C:18]([OH:21])=[CH:19][CH:20]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[CH:4][CH:3]=1.[CH3:25][C:24]([C:26]1[CH:31]=[CH:30][C:29]([OH:32])=[CH:28][CH:27]=1)([C:33]1[CH:34]=[CH:35][C:36]([OH:39])=[CH:37][CH:38]=1)[CH3:23].[CH2:40]1[O:42][CH:41]1[CH2:43][Cl:44]