HRID968183

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10910823

未命名化合物

结构：CC(C)(C)OC(=O)C(CCNCCCCNCCCN)N(C(=O)OC(C)(C)C)C(=O)OC(C)(C)C

HCID22610912

未命名化合物

PRODUCTS

生成物

HCID1103

N1,N4-Bis(3-aminopropyl)-1,4-butanediamine

C10H26N4

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID23938

Palladium

PROCEDURE

实验过程

Monoquaternary spermine containing hydrophilic head-group was prepared in a similar way to compound 3. Briefly, TriBoc-Spermine was reacted with excess of 1-azido-3-iodo-propane in the presence of excess TBA. The resulting quaternarized derivative was hydrogenised under (Pd—C) and Boc protecting group were removed using gaseous HCl in dry methanol.

WORKUP

后处理

customwere removed