HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Methoxybenzaldehyde → Methyl 2-[2-(4-methoxyphenyl)ethenyl]benzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Methoxybenzaldehyde | HCID 31244 | — |
| Reactant | 1,5-Diazabicyclo(4.3.0)non-5-ene | HCID 76349 | — |
| Reactant | {[2-(Methoxycarbonyl)phenyl]methyl}(triphenyl)phosphanium bromide | HCID 10743695 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | Methyl 2-[2-(4-methoxyphenyl)ethenyl]benzoate | HCID 69409617 | — |
Reaction Steps
In 50 ml of acetonitrile were dissolved 4.91 g (10 mmol) of 2-methoxycarbonylbenzyltriphenylphosphonium bromide and 1.77 g (13 mmol) of 4-methoxybenzaldehyde, and 2.48 g (20 mmol) of 1,5-diazabicyclo[4.3.0]-5-nonene was added to the solution and the mixture was refluxed for 5 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07309718B2 |
| Source dataset | uspto-grants-2007_12 |
| ORD ID | ord-b3e670cc92b34ebd97673e10fa08783d |
| Source note | uspto-grants-2007_12 |