HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Methoxy-2-aminobenzothiazole → 2-Amino-4-hydroxybenzothiazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Methoxy-2-aminobenzothiazole | HCID 21622 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Solvent | Ethanethiol | HCID 6343 | — |
| Product | 2-Amino-4-hydroxybenzothiazole | HCID 24057 | — |
Reaction Steps
A solution of AlCl3 (5 mmole) in EtSH (10 mL) was cooled to 0° C. and treated with 2-amino-4-methoxybenzothiazole (1 mmole). The mixture was stirred at 0–5° C. for 2 h. Evaporation and extraction gave 2-amino-4-hydroxybenzothiazole as white solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07312219B2 |
| Source dataset | uspto-grants-2007_12 |
| ORD ID | ord-81607eb7065443e38d9cae577c238bfb |
| Source note | uspto-grants-2007_12 |