HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyltributylstannane → 1-(Ethoxymethoxy)-2-methyl-4-(prop-2-en-1-yl)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyltributylstannane | HCID 90628 | — |
| Reactant | 4-Bromo-1-ethoxymethoxy-2-methylbenzene | HCID 17983090 | — |
| Catalyst | HCID 178479802 | HCID 178479802 | — |
| Product | 1-(Ethoxymethoxy)-2-methyl-4-(prop-2-en-1-yl)benzene | HCID 17983071 | — |
Reaction Steps
In a manner similar to Example 1c, by reacting 16 g (65 mmol) of 4-bromo-1-ethoxymethoxy-2-methylbenzene with 30 ml (97 mmol) of allyltributyltin and 1.35 g (2 mmol) of dichlorobis (triphenylphosphino)palladium. A yellow oil is obtained (m=12:1 g, y=89%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07312249B2 |
| Source dataset | uspto-grants-2007_12 |
| ORD ID | ord-afdb249f82e84ca3b318b362c496c5e0 |
| Source note | uspto-grants-2007_12 |