3-Chlorothiophenol → 6-benzenesulfonyl-3,4-dihydro-2H-naphthalen-1-one

HRID 971273Notes

Reaction equation

ClC1C=C(S)C=CC=1.Cl[C:10]1[CH:11]=[C:12]([S:16]([C:19]2[CH:20]=[C:21]3[C:26](=[CH:27][CH:28]=2)[C:25](=[O:29])[CH2:24][CH2:23][CH2:22]3)(=[O:18])=[O:17])[CH:13]=[CH:14][CH:15]=1>>[C:12]1([S:16]([C:19]2[CH:20]=[C:21]3[C:26](=[CH:27][CH:28]=2)[C:25](=[O:29])[CH2:24][CH2:23][CH2:22]3)(=[O:18])=[O:17])[CH:11]=[CH:10][CH:15]=[CH:14][CH:13]=1

Participants

Reactant 2

HCID 162573-Chlorothiophenol

HCID 666511846-(3-chloro-benzenesulfonyl)-3,4-dihydro-2H-naphthalen-1-one

Product 1

HCID 590217396-benzenesulfonyl-3,4-dihydro-2H-naphthalen-1-one

Procedure

Similarly prepared using the above procedure with 3-chlorobenzenethiol in step 4, was 6-(3-chloro-benzenesulfonyl)-3,4-dihydro-2H-naphthalen-1-one. MS: 287 (M+H)+.

Workup

customSimilarly prepared

Sources & evidence

ORD record: ord-91891b23503e4ea3988dfc305607ab62
Source dataset: uspto-grants-2007_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07312359B2

Reaction notes

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