HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acrolein → Dimethyl 2-formyl-3-methylcyclopropane-1,1-dicarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acrolein | HCID 7847 | — |
| Reactant | Hexenal | HCID 10460 | — |
| Reactant | 2-Pentenal | HCID 12993 | — |
| Reactant | Crotonaldehyde | HCID 447466 | — |
| Reactant | Acetic acid trans-4-oxo-but-2-enyl ester | HCID 11535561 | — |
| Product | Dimethyl 2-formyl-3-methylcyclopropane-1,1-dicarboxylate | HCID 12729146 | — |
| Product | Dimethyl 3-(acetoxymethyl)-2-formylcyclopropane-1,1-dicarboxylate | HCID 21312667 | — |
| Product | Dimethyl 2-formyl-3-ethylcyclopropane-1,1-dicarboxylate dimethyl 2-formyl-3-propylcyclopropane-1,1-dicarboxylate | HCID 86736587 | — |
Reaction Steps
In the same manner but replacing acrolein with an equivalent amount of crotonaldehyde, 2-pentenal, 2-hexenal or γ-acetoxycrotonaldehyde, the following compounds of formula V, dimethyl 2-formyl-3-methylcyclopropane-1,1-dicarboxylate, dimethyl 2-formyl-3-ethylcyclopropane-1,1-dicarboxylate dimethyl 2-formyl-3-propylcyclopropane-1,1-dicarboxylate, dimethyl 3-(acetoxymethyl)-2-formylcyclopropane-1,1-dicarboxylate are obtained, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04161608 |
| Source dataset | uspto-grants-1979_07 |
| ORD ID | ord-88c1e95af60c4d3a85051080473e97f0 |
| Source note | uspto-grants-1979_07 |