HRID972110

反应详情

EQUATION

反应方程式

HRID 972110 的结构方程式

AUXILIARIES

试剂、催化剂与溶剂

1

PROCEDURE

实验过程

30 g (0.184 mol) of potassium dimethylmaleimide are suspended in 175 g (1.89 mols) of epichlorohydrin. After adding 0.05 g of tetramethylammonium chloride, the mixture is heated, whilst stirring, and boiled under reflux for 18 hours and is then filtered. After removing the unconverted chlorohydrin by distillation under a waterpump vacuum, about 30 g of a viscous, pale brown liquid which has an epoxide content of 4.9 equivalents/kg (calculated: 5.5 equivalents/kg) remain. The NMR spectrum of the product corresponds to N-glycidyl-dimethylmaleimide of the formula ##STR30##

WORKUP

后处理

  1. temperaturethe mixture is heated
  2. temperatureunder reflux for 18 hours
  3. filtrationis then filtered
  4. customAfter removing the unconverted chlorohydrin
  5. distillationby distillation under a waterpump vacuum, about 30 g of a viscous, pale brown liquid which