HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium hydride → 2-Methylbenzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | Trimethylsulfonium iodide | HCID 75127 | — |
| Reactant | 2-(2-Methylphenyl)oxirane | HCID 151042 | — |
| Product | 2-Methylbenzaldehyde | HCID 10722 | — |
Reaction Steps
Following the procedure of Example 9 and employing a 57% dispersion sodium hydride in mineral oil (4.84 g., 0.115 mol), 23.5 g. (0.115 mol) of trimethylsulfonium iodide and 11.5 g. (0.0926 mol) of o-tolualdehyde there is obtained o-methylstyrene oxide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04052506 |
| Source dataset | uspto-grants-1977_10 |
| ORD ID | ord-1af41ee7de5a40938f6a406f6911b61f |
| Source note | uspto-grants-1977_10 |