HuagongsheHuagongshe Chemistry Print Report · For research reference only
Piperonal → HCID 53891596, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Piperonal | HCID 8438 | — |
| Reactant | 4-Morpholinepropanenitrile | HCID 78298 | — |
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | HCID 53891596 | HCID 53891596 | — |
Reaction Steps
β-Morpholinopropionitrile (20 g.), dimethylsulphoxide (30 ml.), and sodium methoxide (1 g.) were heated together at 80° C and a solution of piperonaldehyde (19 g.) in dimethylsulphoxide was added. The mixture was reacted at 80° C for 15 min., and on work-up gave β-morpholino-α-piperonylacrylonitrile. Wt.=21 g. (61%) m.p. 85°-85.5° C (recrystallised from methanol).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04052553 |
| Source dataset | uspto-grants-1977_10 |
| ORD ID | ord-4b9fa2d8e4ab481ab113e8f5a3959782 |
| Source note | uspto-grants-1977_10 |