HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl 3,7-dimethyl-8-oxoocta-2,4,6-trienoate → 9-(6-Chloro-4-methoxy2,5-dimethyl-phenyl)-3,7-dimethyl-nona-2,4,6,8-tetraen-1-oic acid ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl 3,7-dimethyl-8-oxoocta-2,4,6-trienoate | HCID 54295620 | — |
| Reactant | HCID 86735156 | HCID 86735156 | — |
| Product | 9-(6-Chloro-4-methoxy2,5-dimethyl-phenyl)-3,7-dimethyl-nona-2,4,6,8-tetraen-1-oic acid ethyl ester | HCID 135389 | — |
Reaction Steps
By the procedure of Example 1, 6-chloro-4-methoxy-2,5-dimethylbenzyl-triphenylphosphonium chloride is reacted with 7-formyl-3-methyl-octa-2,4,6-trien-1-oic acid ethyl ester to obtain 9-(6-chloro-4-methoxy-2,5-dimethyl-phenyl)-3,7-dimethyl-nona-2,4,6,8-tetraen-1-oic acid ethyl ester of melting point 106°-107° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04054589 |
| Source dataset | uspto-grants-1977_10 |
| ORD ID | ord-5ab872d3477848578b03f73a0d51e4e8 |
| Source note | uspto-grants-1977_10 |