Hydrochloric Acid → HCID 86734012, compound

Participants

Reaction Conditions

Reaction Steps

To a solution of 1.00 g. (0.00308 mole) of 2-(carbethoxymethyl)-3-(1-trans-octenyl)-1,1-dioxolano cyclopentane in 5 ml. of heptane at -78° C. and under nitrogen is added dropwise 2.60 ml. of a solution of 25% diisobutylaluminum hydride in hexane. The resulting solution is stirred at -78° C. for 2.5 hours and then poured into cold dilute hydrochloric acid. The organic phase is washed with saturated brine, dried (Na2SO4), and evaporated to yield 0.863 g. of a colorless oil. IR 2695, 1723, 1045, 970 cm-1.

Provenance & Evidence