HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → HCID 86745193, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Methyl cyanoacetate | HCID 7747 | — |
| Reactant | HCID 308743 | HCID 308743 | — |
| Reactant | Ammonium Acetate | HCID 517165 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 86745193 | HCID 86745193 | — |
Reaction Steps
15 g (70 millimoles) of 2-chloro-5-nitrocinnamaldehyde (mp. 115°-117° C.) and 10 g (0.1 mole) of methyl cyanoacetate in 200 ml of toluene were heated under a water separator in the presence of 1 g of ammonium acetate and 1 ml of acetic acid until water no longer distilled over. The product crystallized out on cooling. After the usual working up procedure, 58% of the product of melting point 193°-194° C. remained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05062884 |
| Source dataset | uspto-grants-1991_11 |
| ORD ID | ord-f59dddaa4dd14512bbb2470e198baf52 |
| Source note | uspto-grants-1991_11 |