HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dicyclohexylcarbodiimide → HCID 54140684, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dicyclohexylcarbodiimide | HCID 10868 | — |
| Reactant | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | 1-octanol, 3,7-dimethyl-, (s)- | HCID 6992239 | — |
| Reactant | HCID 12715082 | HCID 12715082 | — |
| Reactant | HCID 21705264 | HCID 21705264 | — |
| Reactant | HCID 178418546 | HCID 178418546 | — |
| Catalyst | 4-(Dimethylamino)pyridine | HCID 14284 | — |
| Solvent | Toluene | HCID 1140 | — |
| Solvent | Diethylene Glycol | HCID 8117 | — |
| Product | HCID 54140684 | HCID 54140684 | — |
Reaction Steps
25 mmol of 4,4"-terphenyldicarboxylic acid (obtainable by reaction of dibromoterphenyl with CuCN in NMP and hydrolysis of the dinitrile with KOH in diethylene glycol), 7.9 g of (S)-3,7-dimethyloctanol and 0.12 g of DMAP are taken in 40 ml of toluene. A solution of 9.9 g of DCC in 15 ml of toluene is added dropwise at room temperature, with stirring, the mixture is stirred overnight and chromatographed with toluene on silica gel and the product is recrystallized to give 4,4"-bis-(3,7-dimethyloctyloxycarbonyl)-p-terphenyl.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05064569 |
| Source dataset | uspto-grants-1991_11 |
| ORD ID | ord-586ead16baab4333ab01123c61c535bf |
| Source note | uspto-grants-1991_11 |