1-Butanol → Butyl 4-(4,6-bis(trichloromethyl)-s-triazin-2-yl)benzoate

HRID 973810Notes

Reaction equation

HRID 973810 reaction equation
[Cl:1][C:2]([Cl:23])([Cl:22])[C:3]1[N:8]=[C:7]([C:9]([Cl:12])([Cl:11])[Cl:10])[N:6]=[C:5]([C:13]2[CH:21]=[CH:20][C:16]([C:17](Cl)=[O:18])=[CH:15][CH:14]=2)[N:4]=1.C([OH:28])CCC.[C:29]1(C)C=C[CH:32]=[CH:31][CH:30]=1>N1C=CC=CC=1>[Cl:11][C:9]([Cl:10])([Cl:12])[C:7]1[N:8]=[C:3]([C:2]([Cl:23])([Cl:22])[Cl:1])[N:4]=[C:5]([C:13]2[CH:21]=[CH:20][C:16]([C:17]([O:18][CH2:29][CH2:30][CH2:31][CH3:32])=[O:28])=[CH:15][CH:14]=2)[N:6]=1

Participants

5

Reactant 3

HCID 2631-ButanolHCID 1140TolueneHCID 14473251HCID 14473251, compound

Product 1

HCID 19989297Butyl 4-(4,6-bis(trichloromethyl)-s-triazin-2-yl)benzoate

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Conditions

Temperature
15 °C

Procedure

4-(4,6-Bis(trichloromethyl)-s-triazin-2-yl)-benzoyl chloride (9 pw) and n-butanol (1 pw) are added to dry toluene (100 pw). The mixture is stirred at 15° C., and 1.9 pw of pyridine is added dropwise. Stirring is continued for 3 hours. The resulting mixture is washed with 2% strength hydrochloric acid, 2% strength sodium hydroxide solution and then with water. After drying of the organic phase over magnesium sulfate, the solvent is removed by distillation, and the residue is recrystallized from ethanol. M.p. 109 to 110° C.

Workup

  1. stirringStirring
  2. washThe resulting mixture is washed with 2% strength hydrochloric acid, 2% strength sodium hydroxide solution
  3. dry with materialAfter drying of the organic phase over magnesium sulfate
  4. customthe solvent is removed by distillation
  5. customthe residue is recrystallized from ethanol

Sources & evidence

ORD record
ord-3fc9537ad5844ffca805ef0592a35865
Source dataset
uspto-grants-1991_11
Patent number
US05064959

Reaction notes

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