Sodium hydrosulfide → HCID 178469412, compound

HRID 973836Notes

Reaction equation

HRID 973836 reaction equation
Cl[C:2]1[N:7]2[N:8]=[C:9]([CH3:11])[N:10]=[C:6]2[N:5]=[C:4]([C:12]([O:14][CH2:15][CH3:16])=[O:13])[CH:3]=1.[SH-:17].[Na+]>O>[CH2:15]([O:14][C:12]([C:4]1[CH:3]=[C:2]([SH:17])[N:7]2[N:8]=[C:9]([CH3:11])[N:10]=[C:6]2[N:5]=1)=[O:13])[CH3:16]

Participants

4

Reactant 2

HCID 28015Sodium hydrosulfideHCID 19989216HCID 19989216, compound

Product 1

HCID 178469412HCID 178469412, compoundYield 74.1%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The product obtained in Step 2 (15 g) was added all at once at room temperature to a solution of sodium hydrosulfide (15 g) in 300 ml of water with stirring under a nitrogen stream, and the reaction mixture was worked up in the same manner as Step 3 of Example 37, affording 11 g of the objective compound as yellow crystals.

Sources & evidence

ORD record
ord-6b090fd0c0e7443c8fa80ea9fcc972dd
Source dataset
uspto-grants-1991_11
Patent number
US05064953

Reaction notes

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