HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl chloride → HCID 54121436, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl chloride | HCID 7412 | — |
| Reactant | Diazomethane | HCID 9550 | — |
| Reactant | Oxalyl chloride | HCID 65578 | — |
| Reactant | Potassium | HCID 5462222 | — |
| Reactant | HCID 54570032 | HCID 54570032 | — |
| Catalyst | Silver(II) oxide | HCID 92152 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 54121436 | HCID 54121436 | — |
Reaction Steps
4-(2-Methyl-2-(4-(3-methyl-2-butenoxy)phenyl)ethenyl)benzoic acid is converted to the corresponding benzoyl chloride by treating the potassium salt of the acid with oxalyl chloride as described in Example 12. The benzoyl chloride is reacted with diazomethane and the resulting diazoketone is decomposed using silver oxide catalyst in methanol to give methyl 4-(2-methyl-2-(4-(3-methyl-2-butenoxy)phenyl)ethenyl)phenylacetate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05068252 |
| Source dataset | uspto-grants-1991_11 |
| ORD ID | ord-fb5bd750c4454071afb50a8ce7e1f3b3 |
| Source note | uspto-grants-1991_11 |