Ammonia → HCID 15924267, compound

HRID 974250Notes

Reaction equation

HRID 974250 reaction equation
[C:1]1([C:7]2[C:16]3[C:15](=[O:17])[CH2:14][CH2:13][CH2:12][C:11]=3[O:10][C:9](=O)[CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[NH3:19]>>[C:1]1([C:7]2[C:16]3[C:15](=[O:17])[CH2:14][CH2:13][CH2:12][C:11]=3[NH:19][C:9](=[O:10])[CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 222AmmoniaHCID 15924266HCID 15924266, compound

Product 1

HCID 15924267HCID 15924267, compound

Procedure

Prepared from 4-phenyl-5,6,7,8-tetrahydro-cumarin- 5-one (melting point: 167°-168° C., prepared from ethyl benzoylacetate and cyclohexan-1,3-dione) and methanolic ammonia in an autoclave over a period of one hour at 135° C.

Sources & evidence

ORD record
ord-aab0d4a64444497d85b57c4405b8d6a7
Source dataset
uspto-grants-1991_11
Patent number
US05068334

Reaction notes

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