Diisobutylamine → Lithium diisobutylamide

HRID 974373Notes

Reaction equation

HRID 974373 reaction equation
[CH2:1]([NH:5][CH2:6][CH:7]([CH3:9])[CH3:8])[CH:2]([CH3:4])[CH3:3].C([Li:14])CCC>C1(C)C=CC=CC=1>[CH2:1]([N-:5][CH2:6][CH:7]([CH3:9])[CH3:8])[CH:2]([CH3:4])[CH3:3].[Li+:14]

Participants

4

Reactant 2

HCID 8085DiisobutylamineHCID 178418339Butyllithium

Product 1

HCID 11018925Lithium diisobutylamide

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Following the process disclosed in application Ser. No. 374,740, 0.22 moles of diisobutyl amine was added to 100 ml of a 2.2M solution of n-butyl lithium in toluene. A clear solution of lithium diisobutylamide was obtained.

Sources & evidence

ORD record
ord-d48a8419adcc4edf9983448ef67ce60e
Source dataset
uspto-grants-1991_11
Patent number
US05068368

Reaction notes

Loading…