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HRID975672

反应详情

EQUATION

反应方程式

HRID 975672 的结构方程式

REACTANTS

反应物

2
结构：C=CCOC(=O)N1C[C@H](OS(C)(=O)=O)C[C@H]1CCOS(C)(=O)=O
HCID15537962

未命名化合物

结构：CC(C)(C)[Si](C)(C)OCc1ncc[nH]1
HCID21745105

未命名化合物

PRODUCTS

生成物

1
结构：C=CCOC(=O)N1C[C@H](OS(C)(=O)=O)C[C@H]1CCn1ccnc1CO[Si](C)(C)C(C)(C)C
HCID54342959

未命名化合物

收率 91.2%

PROCEDURE

实验过程

(2R,4R)-1-Allyloxycarbonyl-4-methylsulfonyloxy-2-(2-methylsulfonyloxyethyl) pyrrolidine (28.8 g) and 2-(t-butyldimethylsilyloxymethyl)imidazole (18.1 g) were reacted in substantially the same manner as that of Preparation 10-3) to give (2R,4R)-1-allyloxycarbonyl-2-[2-(2-(t-butyldimethylsilyloxymethyl) imidazol-1-yl)ethyl]-4-methylsulfonyloxypyrrolidine (34.5 g) as a yellow paste.

WORKUP

后处理

  1. customof Preparation 10-3)