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HRID975705

反应详情

EQUATION

反应方程式

HRID 975705 的结构方程式

REACTANTS

反应物

3
结构：C=CCOC(=O)N1C[C@H](OS(C)(=O)=O)C[C@H]1CCOS(C)(=O)=O
HCID15537962

未命名化合物

结构：CC(C)(C)[O-].[K+]
HCID23665647

2-Methyl-2-propanol, potassium salt

C4H9KO

结构：CC(C)(C)[Si](C)(C)OCc1c[nH]cn1
HCID178455170

未命名化合物

PRODUCTS

生成物

1
结构：C=CCOC(=O)N1C[C@H](OS(C)(=O)=O)C[C@H]1CCn1cnc(CO[Si](C)(C)C(C)(C)C)c1
HCID54108174

未命名化合物

收率 136.7%

PROCEDURE

实验过程

(2R,4R)-1-Allyloxycarbonyl-4-methanesulfonyloxy-2-(2-methanesulfonyloxyethyl)pyrrolidine (13.2 g) was reacted with 4-(t-butyldimethylsilyloxymethyl)imidazol (8.30 g) and potassium t-butoxide (4.39 g) in substantially the same manner as Preparation 10-3) to give (2R,4R)-1-allyloxycarbonyl-2-[2-{4-(t-butyldimethylsilyloxymethyl)-imidazol-1-yl}ethyl]-4-methanesulfonyloxypyrrolidine (23.7 g) as a brown paste.

WORKUP

后处理

  1. customas Preparation 10-3)