HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → HCID 53957164, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | ethyl N-ethoxycarbonyliminocarbamate | HCID 220568 | — |
| Reactant | HCID 54432884 | HCID 54432884 | — |
| Reactant | HCID 178526132 | HCID 178526132 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 53957164 | HCID 53957164 | — |
Reaction Steps
(2R,4R)-1-Allyloxycarbonyl-4-hydroxy-2-[2-(1,2, 4-triazol-1-yl)ethyl]pyrrolidine (5.82 g) was reacted with triphenylphosphine (8.62 g), diethyl azodicarboxylate (5.17 ml) and thiobenzoic acid (4.64 ml) in tetrahydrofuran (58 ml) in the same manner as Preparation 3-6) to give (2R,4S)-1-allyloxycarbonyl-4-benzoylthio-2-[2-(1,2, 4-triazol-1-yl)ethyl]pyrrolidine (7.92 g) as a yellow paste.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05608056 |
| Source dataset | uspto-grants-1997_03 |
| ORD ID | ord-1ce88c2ad5f74c9482806478dd1d0bab |
| Source note | uspto-grants-1997_03 |