Water → HCID 178419936, compound

HRID 976124Notes

Reaction equation

HRID 976124 reaction equation
[C:1]([C:3]1[CH:12]=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=1)#[N:2].[N-:13]=[N+:14]=[N-:15].[Na+].[Cl-].[Li+].O>COCCO>[CH:4]1[C:5]2[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=2)[CH:11]=[CH:12][C:3]=1[C:1]1[NH:15][N:14]=[N:13][N:2]=1

Participants

6

Reactant 4

HCID 962WaterHCID 119442-NaphthalenecarbonitrileHCID 33557Sodium AzideHCID 433294Lithium Chloride

Product 1

HCID 178419936HCID 178419936, compound

Reagents, catalysts & solvents 1

HCID 80192-MethoxyethanolSolvent

Procedure

A mixture of 10 g of 2-cyanonaphthalene, 10.61 g of sodium azide, and 7.67 g of lithium chloride was placed in a reaction vessel, and 240 ml of 2-methoxyethanol serving as a solvent was added thereto. The above mixture was refluxed with stirring for 80 hours. The mixture was cooled to room temperature, and 500 ml of water was added to the mixture.

Workup

  1. customwas placed in a reaction vessel
  2. temperatureThe above mixture was refluxed

Sources & evidence

ORD record
ord-1f2e192af08e41cd954c7a8fe7a98515
Source dataset
uspto-grants-1997_03
Patent number
US05610309

Reaction notes

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