HCID 20205015, compound → HCID 20205014, compound

HRID 978094Notes

Reaction equation

HRID 978094 reaction equation
[CH3:1][O:2][C:3]1[C:4]2[CH:14]=[C:13]([C:15]([F:18])([F:17])[F:16])[CH:12]=[CH:11][C:5]=2[S:6][C:7]=1[C:8](O)=O.COC1C2C=CC=CC=2SC=1C[C:27]([O:29][CH3:30])=[O:28]>>[CH3:1][O:2][C:3]1[C:4]2[CH:14]=[C:13]([C:15]([F:18])([F:17])[F:16])[CH:12]=[CH:11][C:5]=2[S:6][C:7]=1[CH2:8][C:27]([O:29][CH3:30])=[O:28]

Participants

3

Reactant 2

HCID 20205015HCID 20205015, compoundHCID 20205017HCID 20205017, compound

Product 1

HCID 20205014HCID 20205014, compound

Procedure

When 3-methoxy-5-(trifluoromethyl)benzo[b]thiophene-2-carboxylic acid was used in place of the starting benzthiophene of Example C-1, and carried through the same sequence of reactions, methyl 3-methoxy-5-(trifluoromethyl)benzo[b]thiophene-2-acetate is obtained.

Sources & evidence

ORD record
ord-92013f92c196415ba59cea0c6af6113b
Source dataset
uspto-grants-1987_05
Patent number
US04663344

Reaction notes

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