HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aniline → HCID 13137239, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aniline | HCID 6115 | — |
| Reactant | 4-Hydroxy-4-methyl-5-(prop-2-en-1-yl)cyclopent-2-en-1-one | HCID 12879872 | — |
| Catalyst | Triethylamine | HCID 8471 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 13137239 | HCID 13137239 | 96.9% |
Reaction Steps
Into the same flask as used in Example 1, 2-allyl-3-hydroxy-3-methyl-4-cyclopentenone (15.2 g), aniline (30 g), triethylamine (0.8 g) and toluene (45 g) were charged, and the mixture was stirred under a nitrogen stream at a temperature of 40° to 70° C. for 2 hours. After completion of the reaction, the mixture was treated and purified in the same manner as in Example 1 to obtain 2-allyl-3-methyl-4-anilino-2-cyclopentenone (22 g). Yield, 97%. nD20 1.5880.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04665174 |
| Source dataset | uspto-grants-1987_05 |
| ORD ID | ord-ebf88cce87524fd28605d48ae77459f8 |
| Source note | uspto-grants-1987_05 |