HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-Butyl hydroperoxide → HCID 22351550, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-Butyl hydroperoxide | HCID 6410 | — |
| Reactant | 1-(2,2,6,6-Tetramethylpiperidin-4-yl)azepan-2-one | HCID 18551435 | — |
| Catalyst | Molybdenum carbonyl (Mo(CO)6) | HCID 98885 | — |
| Product | HCID 22351550 | HCID 22351550 | — |
Reaction Steps
A sample of 25.2 g (0.1 mole) of N-(2,2,6,6-tetramethylpiperidine-4-yl)-ε-caprolactam is refluxed for 2 hours with 50 ml of 4M tert-butylhydroperoxide in the presence of 0.2 g of molybdenum hexacarbonyl, Mo(CO)6 as described in Example 1, to provide 26.6 g of red solid (99% crude yield). Crystallization from hexane gives orange crystals, m.p. 152°-159° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04665185 |
| Source dataset | uspto-grants-1987_05 |
| ORD ID | ord-0d3e31535cd64472900c80bb4a8c6654 |
| Source note | uspto-grants-1987_05 |