Aluminum(III) Chloride → HCID 13851452, compound

HRID 979205Notes

Reaction equation

HRID 979205 reaction equation
[C:1]([C:4]1[O:5][C:6]2[C:12]([O:13]C)=[CH:11][CH:10]=[C:9]([S:15](=[O:22])(=[O:21])[NH:16][CH2:17][C:18]([OH:20])=[O:19])[C:7]=2[CH:8]=1)(=[O:3])[CH3:2].[Al+3].[Cl-].[Cl-].[Cl-]>ClC1C=CC=CC=1>[C:1]([C:4]1[O:5][C:6]2[C:12]([OH:13])=[CH:11][CH:10]=[C:9]([S:15](=[O:21])(=[O:22])[NH:16][CH2:17][C:18]([OH:20])=[O:19])[C:7]=2[CH:8]=1)(=[O:3])[CH3:2]

Participants

4

Reactant 2

HCID 6451240Aluminum(III) ChlorideHCID 13851435HCID 13851435, compound

Product 1

HCID 13851452HCID 13851452, compound

Reagents, catalysts & solvents 1

HCID 7964ChlorobenzeneSolvent

Conditions

Temperature
130 °C

Procedure

A mixture of 2-acetyl-4-(N-carboxymethylsulfamoyl)-7-methoxybenzofuran and AlCl3 in chlorobenzene was heated at 130° C. to give 2-acetyl-4-(N-carboxymethylsulfamoyl)-7-hydroxybenzofuran.

Sources & evidence

ORD record
ord-409a0a25eaa74bd29eeee184337d657b
Source dataset
uspto-grants-1987_05
Patent number
US04666931

Reaction notes

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