HuagongsheHuagongshe Chemistry Print Report · For research reference only
Quinone → 2,7-Dimethyl-phenothiazone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Quinone | HCID 4650 | — |
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | 2-Amino-3-methoxybenzene-1-thiol | HCID 12631859 | — |
| Product | 2,7-Dimethyl-phenothiazone | HCID 369391 | — |
Reaction Steps
Following the procedure described in Example 10 but substituting 2-amino-5-methylthiophenol for 2-amino-3-methoxythiophenol and substituting 2-methyl-p-benzoquinone for p-benzoquinone, a mixture of the title compounds were obtained. Chromatography on silica gel eluting with 10% EtOAc in CH2Cl2 afforded firstly 2,7-dimethyl-3H-phenothiazin-3-one, m.p. 177° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04667032 |
| Source dataset | uspto-grants-1987_05 |
| ORD ID | ord-a392b68cc4f34487a40933be0fa805fe |
| Source note | uspto-grants-1987_05 |