Sodium Hydroxide → HCID 13922806, compound

HRID 979327Notes

Reaction equation

[C:1]([C:4]1[CH:33]=[CH:32][C:7]([O:8][CH2:9][C:10]2([S:17][C:18]3[CH:23]=[CH:22][C:21]([C:24](=[O:31])[CH2:25][CH2:26][C:27]([O:29]C)=[O:28])=[CH:20][CH:19]=3)[CH2:15][CH2:14][CH2:13][CH2:12][CH:11]2[OH:16])=[C:6]([CH2:34][CH2:35][CH3:36])[C:5]=1[OH:37])(=[O:3])[CH3:2].[OH-].[Na+]>>[C:1]([C:4]1[CH:33]=[CH:32][C:7]([O:8][CH2:9][C:10]2([S:17][C:18]3[CH:19]=[CH:20][C:21]([C:24](=[O:31])[CH2:25][CH2:26][C:27]([OH:29])=[O:28])=[CH:22][CH:23]=3)[CH2:15][CH2:14][CH2:13][CH2:12][CH:11]2[OH:16])=[C:6]([CH2:34][CH2:35][CH3:36])[C:5]=1[OH:37])(=[O:3])[CH3:2]

Participants

Reactant 2

HCID 14798Sodium Hydroxide

HCID 19847772HCID 19847772, compound

Product 1

HCID 13922806HCID 13922806, compound

Procedure

The isomer of the title compound of Step A of Example 2 was treated with sodium hydroxide as described in Step E of Example 1 to afford the title compound, m.p. 65°-67° remelts at 125°-127° C.

Sources & evidence

ORD record: ord-36195d4e9992440ab41c2d7f286248d9
Source dataset: uspto-grants-1987_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04667055

Reaction notes

Loading…