HRID979436

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID980

4-Nitrophenol

C6H5NO3

HCID14797

Potassium hydroxide

HKO

HCID220225

Hexachlorocyclotriphosphazene

Cl6N3P3

PRODUCTS

生成物

结构：O=[N+]([O-])c1ccc(OP2(Oc3ccc([N+](=O)[O-])cc3)=NP(Oc3ccc([N+](=O)[O-])cc3)(Oc3ccc([N+](=O)[O-])cc3)=NP(Oc3ccc([N+](=O)[O-])cc3)(Oc3ccc([N+](=O)[O-])cc3)=N2)cc1

HCID272994

未命名化合物

PROCEDURE

实验过程

This material is prepared according to the method of Kober et al., Inorganic Chemistry, Vol. 5, p. 2239 (1966), which is incorporated herein by reference, by treatment of hexachlorocyclotriphosphazene with p-nitrophenol and potassium hydroxide. Hexakis(4-nitrophenoxy)-cyclotriphosphazene having a melting point of 261°-264° C. is obtained (lit. m.p. 264° C.). The infrared spectrum (in KBr), (cm-1) is 1589 (aromatic), 1522 and 1348 (asymmetrical and symmetrical nitro group stretching) and 1203, 1182 and 1163 (cyclotriphosphazene P=N).

WORKUP

后处理

customThis material is prepared

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-bae3662249dc4ab7a27eabf583804785
来源数据集: uspto-grants-1987_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04668589
来源说明: uspto-grants-1987_05

反应 SMILES

Cl[P:2]1(Cl)[N:7]=[P:6](Cl)(Cl)[N:5]=[P:4](Cl)(Cl)[N:3]=1.[CH:13]1[C:18]([N+:19]([O-:21])=[O:20])=[CH:17][CH:16]=[C:15]([OH:22])[CH:14]=1.[OH-:23].[K+]>>[N+:19]([C:18]1[CH:17]=[CH:16][C:15]([O:22][P:2]2([O:22][C:15]3[CH:16]=[CH:17][C:18]([N+:19]([O-:21])=[O:20])=[CH:13][CH:14]=3)[N:7]=[P:6]([O:22][C:15]3[CH:16]=[CH:17][C:18]([N+:19]([O-:21])=[O:20])=[CH:13][CH:14]=3)([O:23][C:15]3[CH:14]=[CH:13][C:18]([N+:19]([O-:21])=[O:20])=[CH:17][CH:16]=3)[N:5]=[P:4]([O:22][C:15]3[CH:16]=[CH:17][C:18]([N+:19]([O-:21])=[O:20])=[CH:13][CH:14]=3)([O:22][C:15]3[CH:16]=[CH:17][C:18]([N+:19]([O-:21])=[O:20])=[CH:13][CH:14]=3)[N:3]=2)=[CH:14][CH:13]=1)([O-:21])=[O:20]