Tetrakis(4-aminophenoxy)bisphenoxycyclotriphosphazene → Tris(4-aminophenoxy)-tris(phenoxy)cyclotriphosphazene

HRID 979438Notes

Reaction equation

HRID 979438 reaction equation
NC1C=CC(OP2(OC3C=CC(N)=CC=3)N=P(OC3C=CC=CC=3)(OC3C=CC=CC=3)N=P(OC3C=CC(N)=CC=3)(OC3C=CC(N)=CC=3)N=2)=CC=1.[NH2:53][C:54]1[CH:105]=[CH:104][C:57]([O:58][P:59]2([O:96][C:97]3[CH:102]=[CH:101][C:100](N)=[CH:99][CH:98]=3)[N:64]=[P:63]([O:72][C:73]3[CH:78]=[CH:77][C:76]([NH2:79])=[CH:75][CH:74]=3)([O:65][C:66]3[CH:71]=[CH:70][CH:69]=[CH:68][CH:67]=3)[N:62]=[P:61]([O:88][C:89]3[CH:94]=[CH:93][C:92]([NH2:95])=[CH:91][CH:90]=3)([O:80][C:81]3[CH:86]=[CH:85][C:84](N)=[CH:83][CH:82]=3)[N:60]=2)=[CH:56][CH:55]=1>>[NH2:53][C:54]1[CH:105]=[CH:104][C:57]([O:58][P:59]2([O:96][C:97]3[CH:102]=[CH:101][CH:100]=[CH:99][CH:98]=3)[N:64]=[P:63]([O:72][C:73]3[CH:74]=[CH:75][C:76]([NH2:79])=[CH:77][CH:78]=3)([O:65][C:66]3[CH:71]=[CH:70][CH:69]=[CH:68][CH:67]=3)[N:62]=[P:61]([O:88][C:89]3[CH:94]=[CH:93][C:92]([NH2:95])=[CH:91][CH:90]=3)([O:80][C:81]3[CH:86]=[CH:85][CH:84]=[CH:83][CH:82]=3)[N:60]=2)=[CH:56][CH:55]=1

Participants

3

Reactant 2

HCID 131715154Tetrakis(4-aminophenoxy)bisphenoxycyclotriphosphazeneHCID 131715155Pentakis(4-aminophenoxy)phenoxycyclotriphosphazene

Product 1

HCID 14274514Tris(4-aminophenoxy)-tris(phenoxy)cyclotriphosphazene

Procedure

Similarly proceeding as is described in Subpart (a) of this preparation using sufficient PtO2 and hydrogen and using the substituted triphosphazene of Preparation C, Subpart (b); Subpart (c) and Subpart (d), there is obtained the corresponding bis(4-aminophenoxy)tetrakisphenoxycyclotriphosphazene; tetrakis(4-aminophenoxy)bisphenoxycyclotriphosphazene; and pentakis(4-aminophenoxy)phenoxycyclotriphosphazene, respectively.

Sources & evidence

ORD record
ord-bd2e6d2e4e894f64bb595d7561e153d7
Source dataset
uspto-grants-1987_05
Patent number
US04668589

Reaction notes

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