HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 979696Generated: October 30, 2026
Phenothiazine → 1-Tritertbutoxysilyl-2-phenylethylene
https://huagongshe.com/reaction/979696
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Phenothiazine | HCID 7108 | — |
| Reactant | Styrene | HCID 7501 | — |
| Reactant | Tris(tert-butoxy)silane | HCID 101075511 | — |
| Solvent | O-Xylene | HCID 7237 | — |
| Product | 1-Tritertbutoxysilyl-2-phenylethylene | HCID 53860936 | 90% |
Reaction Steps
Into a 45 cc Parr bomb was added 2.5 g (0.02 mol) tritertbutoxysilane, 4.2 g (0.04 mol) styrene, 1.0 g xylene, 30 mg phenothiazine and 2000 ppm Ru3CO12 (20 mg). The reaction was heated in a fluidized sand bath at 175° C. for 5 hours. A single product 1-tritertbutoxysilyl-2-phenylethylene was formed in greater than 90% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04668812 |
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| Source dataset | uspto-grants-1987_05 |
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| ORD ID | ord-5307380d0af540fd922425d38500d2c3 |
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| Source note | uspto-grants-1987_05 |
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