HCID 20222569, compound → Tetralin

HRID 979757Notes

Reaction equation

HRID 979757 reaction equation
O1[CH:11]2[C:2]1(C)[CH2:3][C:4]1[C:5](C)(C)[CH:6](C)[CH2:7][C:8](C)(C)[C:9]=1[CH2:10]2.O1C2C1CC1C(C)(C)C(C)C(C)(C)C=1C2>>[CH2:8]1[C:9]2[C:4](=[CH:3][CH:2]=[CH:11][CH:10]=2)[CH2:5][CH2:6][CH2:7]1

Participants

3

Reactant 2

HCID 20222569HCID 20222569, compoundHCID 20222571HCID 20222571, compound

Product 1

HCID 8404Tetralin

Procedure

In Examples 13A-13J hereinafter the numerals given after the notation "epoxide" denotes the number of the respective Examples hereinbefore. The preferred compounds are "epoxide 1", "epoxide 2" and "epoxide 8", i.e. the novel epoxides 6,7-epoxy-1,1,4,4,6-pentamethyl-1,2,3,4,5,6,7,8-octahydronaphthalene, 6,7-epoxy-1,1,3,4,4,6-hexamethyl-1,2,3,4,5,6,7,8-octahydronaphthalene and 5,6-epoxy-1,1,2,3,3-pentamethyl-4,5,6,7-tetrahydroindane referred to in Examples 1, 2 and 8, respectively.

Sources & evidence

ORD record
ord-cee700b2fdf049cab141cfc48a7d00c0
Source dataset
uspto-grants-1987_01
Patent number
US04634548

Reaction notes

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