Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Sulfite → 4-Hydroxy-1,1,4,4-tetramethylbutyl peroxyneodecanoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Sulfite | HCID 24437 | — |
| 반응물 | Neodecanoyl chloride | HCID 94502 | — |
| 반응물 | 2,5-Dimethylhexane 2,5-dihydroperoxide | HCID 520470 | — |
| 생성물 | 4-Hydroxy-1,1,4,4-tetramethylbutyl peroxyneodecanoate | HCID 86118590 | 55.1% |
반응 단계
Reacting neodecanoyl chloride with 2,5-dimethyl-2,5-dihydroperoxyhexane followed by reducing the intermediate product with a buffered sodium sulfite solution employing the same procedure as used in preparation of C-5 resulted in the preparation of 4-hydroxy-1,1,4,4-tetramethylbutyl peroxyneodecanoate. The liquid product had an assay of 91.7% and was obtained in a corrected yield of 55.1%. An infrared spectrum of the product showed a broad OH band centered at 3300 to 3500 cm-1.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04634753 |
| 출처 데이터셋 | uspto-grants-1987_01 |
| ORD ID | ord-ae8009b164e641cdab3357e777a547e8 |
| 출처 메모 | uspto-grants-1987_01 |