HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 980041Generated: October 30, 2026
Phosphorus tribromide → HCID 13840545, compound
https://huagongshe.com/reaction/980041
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Phosphorus tribromide | HCID 24614 | — |
| Reactant | 2,2,4,4-Tetramethylpentan-3-ol | HCID 139790 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | HCID 13840545 | HCID 13840545 | — |
Reaction Steps
The alcohol is dissolved in benzene and stirred at 0° C. under argon. A solution of phosphorus tribromide in benzene is added and the mixture is stirred for 2 hours and then heated to 60° C. for 4 hours. The mixture is cooled, poured into ice and extracted with ether. The organic layer is washed with saturated NaHCO3, dried over MgSO4 and evaporated to give di-t-butylmethyl bromide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04634792 |
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| Source dataset | uspto-grants-1987_01 |
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| ORD ID | ord-3e796199359c407abf9e2fdd9330be7c |
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| Source note | uspto-grants-1987_01 |
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