HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → 2-(2-Bromo-1,1,2,2-tetrafluoroethylthio)-1,3-dichlorobenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 1,2-Dibromo-1,1,2,2-tetrafluoroethane | HCID 31301 | — |
| Reactant | Benzenethiol, 2,6-dichloro- | HCID 90671 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 2-(2-Bromo-1,1,2,2-tetrafluoroethylthio)-1,3-dichlorobenzene | HCID 20222416 | 35.2% |
Reaction Steps
In a manner similar to Step A of Example 1, the reaction of 26.0 g (0.25 mole) 2,6-dichlorothiophenol, 20.0 g (0.15 mole) potassium carbonate and 75.4 g (0.30 mole) 1,2-dibromotetrafluoroethane in 200 ml of N,N-dimethylformamide produced 31.5 g of 2-(2-bromo-1,1,2,2-tetrafluoroethylthio)-1,3-dichlorobenzene as an oil. The nmr and ir spectra were consistent with the proposed structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04636523 |
| Source dataset | uspto-grants-1987_01 |
| ORD ID | ord-0cfe2562272e4f6a98af5964c297079a |
| Source note | uspto-grants-1987_01 |