HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Peroxide → 6-Hydroxy-2-naphthoic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | Perchloric Acid | HCID 24247 | — |
| Reactant | 6-(2-Hydroxy-2-propyl)naphthalene-2-carboxylic acid | HCID 13782368 | — |
| Reactant | 6-(2-Hydroperoxypropan-2-yl)naphthalene-2-carboxylic acid | HCID 13782369 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | 6-Hydroxy-2-naphthoic acid | HCID 85557 | — |
Reaction Steps
The thus obtained white microcrystals consisting of 6-(2-hydroperoxy-2-propyl)naphthalene-2-carboxylic acid and 6-(2-hydroxy-2-propyl)naphthalene-2-carboxylic acid were reacted in acetonitrile at 50° C. for 30 minutes in the presence of hydrogen peroxide and perchloric acid. Thus, the two compounds were subjected to acid decomposition to form 6-hydroxynaphthalene-2-carboxylic acid almost quantitatively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04638087 |
| Source dataset | uspto-grants-1987_01 |
| ORD ID | ord-1fab9ee774c44d32b15dfecee500a8f5 |
| Source note | uspto-grants-1987_01 |