(+-)-alpha-Pinene → alpha-Pinene oxide

HRID 980861Notes

Reaction equation

HRID 980861 reaction equation
[CH3:1][C:2]1[CH:7]2[C:8]([CH3:10])([CH3:9])[CH:5]([CH2:6]2)[CH2:4][CH:3]=1.C1C(C(OO)=[O:18])=CC=CC=1>C(Cl)(Cl)Cl>[CH3:9][C:8]1([CH3:10])[CH:7]2[C:2]3([CH3:1])[O:18][CH:3]3[CH2:4][CH:5]1[CH2:6]2

Participants

4

Reactant 2

HCID 6654(+-)-alpha-PineneHCID 523077Perbenzoic acid

Product 1

HCID 91508alpha-Pinene oxide

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

in a first stage, epoxidizing α-pinene with a 15-30% solution of perbenzoic acid in chloroform at a temperature between -1° C. and -10° C. to obtain α-pinene epoxide

Workup

  1. customat a temperature between -1° C. and -10° C.

Sources & evidence

ORD record
ord-b2bfbc5244d149649e5b747717bc3047
Source dataset
uspto-grants-1987_01
Patent number
US04639469

Reaction notes

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