Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Benzaldehyde | HCID 240 | — |
| Reactant | Benzylamine | HCID 7504 | — |
| Reactant | Glutaric anhydride | HCID 7940 | — |
| Solvent | O-Xylene | HCID 7237 | — |
| Product | 94655-32-0 | HCID 13772099 | 69% |
Reaction Steps
11.4 g (0.10 mole) of glutaric anhydride and 19.5 g (0.10 mole of Schiff base, prepared from benzaldehyde and benzylamine, are refluxed in 300 ml of xylene at 140° C. for 10 hr. After cooling to 0° C. the solid is collected, washed with xylene and ether: 24.7 g (80%) of acid. Recrystallization from acetone-ether gave 21.3 g (69%) of title compound mp 171°-4° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04639529 |
|---|
| Source dataset | uspto-grants-1987_01 |
|---|
| ORD ID | ord-a7ff1144ee004eeebb96e5e343cd716d |
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| Source note | uspto-grants-1987_01 |
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