HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 19824186, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | Hexane | HCID 8058 | — |
| Reactant | Phenol, 2,6-bis(1,1-dimethylethyl)-4-nitroso- | HCID 70383 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | HCID 19824186 | HCID 19824186 | — |
Reaction Steps
A 2 liter Parr bomb was charged with 210.5 g of 44.6% water wet (0.5 mole, pure, dry) 2,6-di-tert-butyl-4-nitrosophenol, 2.0 g of 5% Pd/C catalyst, 300 ml dichloromethane and 400 ml hexane. The nitrogen purged system was pressurized to 50 psi with hydrogen and the rate of hydrogen uptake noted. Hydrogenation was completed within one hour.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04990671 |
| Source dataset | uspto-grants-1991_02 |
| ORD ID | ord-89e4a46da6b64ab080f7764d88a2ecde |
| Source note | uspto-grants-1991_02 |