HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl Acrylate → Methyl bicyclo[2.2.1]hept-5-ene-2-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl Acrylate | HCID 7294 | — |
| Reactant | Cyclopentadiene | HCID 7612 | — |
| Reactant | Ethylidenenorbornene | HCID 27756 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | Methyl bicyclo[2.2.1]hept-5-ene-2-carboxylate | HCID 250075 | — |
Reaction Steps
Commercially available ethylidenenorbornene (called "EN" hereinafter) was used as the third comonomer. 82.5 g of methyl-acrylate was reacted with 54 g of cyclopentadiene in ether, and the product was purified by distillation to produce 91 g of 5-methoxycarbonylnorbornene (called "MCN" hereinafter) which was also used as the third comonomer.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04994535 |
| Source dataset | uspto-grants-1991_02 |
| ORD ID | ord-655bcfa97b6641809fc90e55b0741e7d |
| Source note | uspto-grants-1991_02 |